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These mixtures are the major occupants of Region IV in Fig 165 Since neither species associates by hydrogen bonding, attractions between like species result from dispersion, induction, and dipoleldipole interactions The same kinds of interaction obtain for unlike molecules, but in addition there is superposed a strong attraction owing to the formation of a hydrogen-bonded solvation complex The net effect is a negative value for H ~the system is exothermic ;

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All four types of attractive interaction occur between unlike species, and for at least one of the pure species Thus the sign and magnitude of H E reflect a balance between competing effects of dipoleldipole interactions, association, and solvation Qualitative prediction of enthalpic behavior is difficult, except by analogy Figure 165 suggests the diversity of behavior observed for such mixtures

The purpose of the GeneralError global method is simple: communicate to the user that an error occurred, and then move on. It s meant to be simple, and it is simple. You could enhance the routine with some additional features. Logging of the error out to a file (or any other active log listener) might assist you later if you needed to examine application-generated errors. Add the following code to the routine, just after the MsgBox command, to record the exception.

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The excess entropy is related to AS through Eqs (1238) and (1235) Thus,

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(1235)

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An ideal solution is one comprising molecules of identical size and shape, and for which intermolecular forces are the same for all molecular pairs, whether like or unlike For such a hypothetical solution, the entropy change of mixing, given by Eq (1235), is always positive In a real mixture, molecules of different species have different sizes andlor shapes, and the intrinsic strengths of molecular interactions are different for different molecular pairs As a result, AS for a real mixture may be greater or less than a s i d , and by Eq (1626), sE may be positive or negative The behavior of S E is most conveniently rationalized by separate consideration of size/shape effects on the one hand and structural effects on the other (The word "structure" refers to the order brought about at the molecular level by intermolecular forces) Pure sizelshape effects result in a AS greater than AS", and hence provide a positive contribution to sEPrausnitz et a1" discuss the relative roles of size and shape, and give references to the relevant literature If size effects alone are considered, an approximate upper bound to this contribution to S E is given by the Flory-Huggins equation:

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